Placer gold has been reported in small amounts throughout the South Nahanni river drainage; however, the original source of the gold is uncertain. This study focuses on two types of placer gold in the area: (1) locally abundant grains derived from near Selena Creek, and (2) scattered grains recovered from streams throughout the South Nahanni drainage area. A shape analysis of all gold grains was completed and representative grains from each sample population were selected for imaging on the scanning electron microscope, along with analysis for Au-Ag-Cu-Hg values on the electron microprobe. The gold grains are typically >700 fineness and mercury is below detection levels (<0.20%). Approximately half the grains analysed from the Selena Creek area registered near to, or slightly greater than, detection levels of copper (<0.04%), whereas the majority of grains from the isolated showings had copper contents below detection levels. The results are compared with published morphological and compositional data for placer and lode gold in other regions.